DC Field | Value | Language |
---|---|---|
dc.contributor.author | Ryoo, Ryong | ko |
dc.contributor.author | Ko, CH | ko |
dc.contributor.author | Kim, JM | ko |
dc.contributor.author | Howe, R | ko |
dc.date.accessioned | 2009-11-11T09:06:22Z | - |
dc.date.available | 2009-11-11T09:06:22Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 1996 | - |
dc.identifier.citation | CATALYSIS LETTERS, v.37, no.1-2, pp.29 - 33 | - |
dc.identifier.issn | 1011-372X | - |
dc.identifier.uri | http://hdl.handle.net/10203/12445 | - |
dc.description.abstract | Mesoporous molecular sieve MCM-41 with a Si/Al ratio of 35 was obtained by hydrothermal synthesis using a gel mixture with a molar composition of 6 SiO2 : 0.1 Al2O3 : 1 hexadecyltrimethylammonium chloride : 0.25 dodecyltrimethylammonium bromide : 0.25 tetrapropylammonium bromide : 0.15 (NH4)(2)O : 1.5 Na2O : 300 H2O. The MCM-41 sample was calcined in O-2 flow al 813 K and subsequently ion exchanged with Ca2+. A small Pt cluster has been supported on the MCM-41 sample following a procedure using ion exchange of Pt(NH3)(4)(2+). The Pt(NH3)(4)(2+) ion supported on MCM-41 has been activated in O-2 flow at 593 K and subsequently reduced with H-2 flow at 573 K, in the same way used for the preparation of a Pt cluster entrapped inside the supercage of zeolite NaY. The resulting Pt cluster supported on the MCM-41 shows hydrogen chemisorption of total two H atoms per Pt at 296 K (based on the total amount of Pt) and high catalytic activity for hydrogenolysis of ethane. The chemical shift in Xe-129 NMR spectroscopy of adsorbed xenon indicates that the Pt cluster is located inside the mesoporous molecular sieve. | - |
dc.description.sponsorship | RR and RH acknowledge that a part of the present work was performed during Ryoo's sabbatical leave from KAIST at UNSW through financial support from Australian Research Council. | en |
dc.language | English | - |
dc.language.iso | en_US | en |
dc.publisher | BALTZER SCI PUBL BV | - |
dc.subject | ZEOLITE | - |
dc.title | Preparation of nanosize Pt clusters using ion exchange of Pt(NH3)(4)(2+) inside mesoporous channel of MCM-41 | - |
dc.type | Article | - |
dc.identifier.wosid | A1996TZ51000006 | - |
dc.identifier.scopusid | 2-s2.0-0002636313 | - |
dc.type.rims | ART | - |
dc.citation.volume | 37 | - |
dc.citation.issue | 1-2 | - |
dc.citation.beginningpage | 29 | - |
dc.citation.endingpage | 33 | - |
dc.citation.publicationname | CATALYSIS LETTERS | - |
dc.identifier.doi | 10.1007/BF00813515 | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Ryoo, Ryong | - |
dc.contributor.nonIdAuthor | Ko, CH | - |
dc.contributor.nonIdAuthor | Kim, JM | - |
dc.contributor.nonIdAuthor | Howe, R | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | MCM-41 | - |
dc.subject.keywordAuthor | zeolite | - |
dc.subject.keywordAuthor | ion exchange | - |
dc.subject.keywordAuthor | Pt cluster | - |
dc.subject.keywordAuthor | Xe-129 NMR | - |
dc.subject.keywordPlus | ZEOLITE | - |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.