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College of Natural Sciences(자연과학대학)Graduate School of Nanoscience and Technology(나노과학기술대학원)NT-Journal Papers(저널논문)

Stabilization of Sn2+ in K10Sn3(P2Se6)(4) and Cs2SnP2Se6 Derived from a Basic Flux

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dc.contributor.authorChung, Inko
dc.contributor.authorKanatzidis, Mercouri G.ko
dc.date.accessioned2013-03-12T23:08:12Z-
dc.date.available2013-03-12T23:08:12Z-
dc.date.created2013-01-28-
dc.date.created2013-01-28-
dc.date.issued2011-01-
dc.identifier.citationINORGANIC CHEMISTRY, v.50, no.2, pp.412 - 414-
dc.identifier.issn0020-1669-
dc.identifier.urihttp://hdl.handle.net/10203/103813-
dc.description.abstractK10Sn3(P2Se6)(2) and Cs2SnP2Se6 stabilize the lower oxidation state of Sn2+. K10Sn3(P2Se6)(4) crystallizes in the trigonal space group R (3) over bar with a = b = 24.1184(7) angstrom and c = 7.6482(2) angstrom at 100 K. Cs2SnP2Se6 crystallizes in P2./c with a = 10.1160(4) angstrom, b = 12.7867(5) angstrom, c = 11.0828(5) angstrom, and beta = 94.463(3)degrees at 100(2) K. Electronic absorption spectra revealed band gaps of 1.82 eV for K10Sn3(P2Se6)4 and 2.06 eV for Cs2SnP2Se6. Solid-state magic-angle-spinning P-31 NMR, UV-vis, Raman, and IR spectroscopy and thermal analysis studies of the compounds are reported.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectMETAL POLYSELENOPHOSPHATE FLUXES-
dc.subject2ND-HARMONIC GENERATION RESPONSE-
dc.subjectINTERMEDIATE TEMPERATURES-
dc.subjectCRYSTAL-STRUCTURE-
dc.subjectSELENOPHOSPHATE-
dc.subjectRB-
dc.subjectPHOSPHORUS-
dc.subjectTRANSITION-
dc.subjectCOMPLEXES-
dc.subjectSN2P2SE6-
dc.titleStabilization of Sn2+ in K10Sn3(P2Se6)(4) and Cs2SnP2Se6 Derived from a Basic Flux-
dc.typeArticle-
dc.identifier.wosid000285956600006-
dc.identifier.scopusid2-s2.0-78651293920-
dc.type.rimsART-
dc.citation.volume50-
dc.citation.issue2-
dc.citation.beginningpage412-
dc.citation.endingpage414-
dc.citation.publicationnameINORGANIC CHEMISTRY-
dc.identifier.doi10.1021/ic101140r-
dc.contributor.localauthorChung, In-
dc.contributor.nonIdAuthorKanatzidis, Mercouri G.-
dc.type.journalArticleArticle-
dc.subject.keywordPlusMETAL POLYSELENOPHOSPHATE FLUXES-
dc.subject.keywordPlus2ND-HARMONIC GENERATION RESPONSE-
dc.subject.keywordPlusINTERMEDIATE TEMPERATURES-
dc.subject.keywordPlusCRYSTAL-STRUCTURE-
dc.subject.keywordPlusSELENOPHOSPHATE-
dc.subject.keywordPlusRB-
dc.subject.keywordPlusPHOSPHORUS-
dc.subject.keywordPlusTRANSITION-
dc.subject.keywordPlusCOMPLEXES-
dc.subject.keywordPlusSN2P2SE6-
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