Total synthesis of (-)-dysiherbaine
The enantioselective synthesis of (-)-dysiherbaine (1) has been established with efficiency via a unique synthetic strategy involving the desymmetrization of 2-substituted glycerol to install a quaternary chiral carbon, which induces further stereochemistry in the bicyclic perhydrofuropyran through mercuriocyclization and epoxidation.
- Publisher
- ROYAL SOC CHEMISTRY
- Issue Date
- 2012
- Language
- English
- Article Type
- Article
- Keywords
RECEPTOR ION CHANNELS; SPONGE DYSIDEA-HERBACEA; EXCITATORY AMINO-ACIDS; TETHERED AMINOHYDROXYLATION; MARINE SPONGE; STEREOSELECTIVE SYNTHESIS; GLUTAMATE RECEPTORS; KAINATE RECEPTORS; DYSIHERBAINE; CORE
- Citation
CHEMICAL COMMUNICATIONS, v.48, no.50, pp.6295 - 6297
- ISSN
- 1359-7345
- Appears in Collection
- CH-Journal Papers(저널논문)
- Files in This Item
- 000304486800028.pdf(667.06 kB)Download
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