Synthesis in Ionic Liquids: [Bi2Te2Br](AlCl4), a Direct Gap Semiconductor with a Cationic Framework

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The Lewis acidic ionic liquid EMIMBr-AlCl3 (EMIM = 1-ethyl-3-methylimidazolium) allows a novel synthetic route to the semiconducting layered metal chalcogenides halide [Bi2Te2Br](AlCl4) and its Sb analogue. [Bi2Te2Br](AlCl4) is a direct band gap, strongly anisotropic semiconductor and consists of cationic infinite layers of [Bi2Te2Br](+) and [AlCl4](-) anions inserted between the layers.
Publisher
AMER CHEMICAL SOC
Issue Date
2010-10
Language
English
Article Type
Article
Keywords

IONOTHERMAL SYNTHESIS; METAL NANOPARTICLES; = K; CHALCOGENIDES; NANORODS; RB; CS; CHEMISTRY; FLUXES; SE

Citation

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.132, no.42, pp.14760 - 14762

ISSN
0002-7863
DOI
10.1021/ja107483g
URI
http://hdl.handle.net/10203/103595
Appears in Collection
NT-Journal Papers(저널논문)
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