Synthesis and Properties of a Polyhedral Oligomeric Silsesquioxane-Based New Light-Emitting Nanoparticle

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A polyhedral oligomeric silsesquioxane (POSS)-based electroluminescent nanoparticle, POSS-NPA, which contains anthracenenaphthyl chromophores on each of its eight arms, was easily prepared via the hydrosilylation reaction between octakis(dimethylsiloxy)silsesquioxane and allyl-functionalized 9-naphthalene-2-yl-10-phenyl anthracene chromophores. POSS-NPA was completely soluble in common organic solvents such as chloroform, THF, toluene, p-xylene, and chlorobenzene, and showed good film-forming properties on a quartz plate or an indium tin oxide (ITO) plate, i.e., it has good solution processing properties. The UV-visible absorption and the photoluminescence (PL) emission maxima of POSS-NPA in chlorobenzene solution were found to be 378 nm and 433 nm while those of POSS-NPA in the solid state were 379 and 464 nm, respectively. An electroluminescent (EL) device with the configuration of ITO/PEDOT:PSS/POSS-NPA (50 nm)/BAlq (40 nm)/LiF (1 nm)/Al (120 nm) was also fabricated and the blue light emission was successfully obtained.
Publisher
AMER SCIENTIFIC PUBLISHERS
Issue Date
2009-12
Language
English
Article Type
Article; Proceedings Paper
Keywords

HYBRID; DERIVATIVES

Citation

JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, v.9, no.12, pp.7029 - 7033

ISSN
1533-4880
DOI
10.1166/jnn.2009.1634
URI
http://hdl.handle.net/10203/102785
Appears in Collection
CH-Journal Papers(저널논문)
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