Dynamic covalent templated-synthesis of [c2] daisy chains

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A couple of [c2] daisy chains have been assembled in each case from four components in quantitative yields at room temperature in acetonitrile as a result of the self-templated clippings of their [24]crown-8 rings by reversible imine bond formation around secondary dialkylammonium recognition sites in their stalks.
Publisher
ROYAL SOC CHEMISTRY
Issue Date
2012
Language
English
Article Type
Article
Keywords

MOLECULAR BORROMEAN RINGS; THERMODYNAMIC CONTROL; DIRECTED SYNTHESIS; DONOR-ACCEPTOR; INTERLOCKED MOLECULES; CLOSING METATHESIS; ROTAXANE FORMATION; OLEFIN METATHESIS; CHEMISTRY; MACROCYCLE

Citation

CHEMICAL COMMUNICATIONS, v.48, no.84, pp.10401 - 10403

ISSN
1359-7345
DOI
10.1039/c2cc35522a
URI
http://hdl.handle.net/10203/101904
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