Dynamic covalent templated-synthesis of [c2] daisy chains
A couple of [c2] daisy chains have been assembled in each case from four components in quantitative yields at room temperature in acetonitrile as a result of the self-templated clippings of their [24]crown-8 rings by reversible imine bond formation around secondary dialkylammonium recognition sites in their stalks.
- Publisher
- ROYAL SOC CHEMISTRY
- Issue Date
- 2012
- Language
- English
- Article Type
- Article
- Keywords
MOLECULAR BORROMEAN RINGS; THERMODYNAMIC CONTROL; DIRECTED SYNTHESIS; DONOR-ACCEPTOR; INTERLOCKED MOLECULES; CLOSING METATHESIS; ROTAXANE FORMATION; OLEFIN METATHESIS; CHEMISTRY; MACROCYCLE
- Citation
CHEMICAL COMMUNICATIONS, v.48, no.84, pp.10401 - 10403
- ISSN
- 1359-7345
- Appears in Collection
- Files in This Item
- 000309189300007.pdf(2.06 MB)Download
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