DC Field | Value | Language |
---|---|---|
dc.contributor.author | Morris, William | ko |
dc.contributor.author | Volosskiy, Boris | ko |
dc.contributor.author | Demir, Selcuk | ko |
dc.contributor.author | Gandara, Felipe | ko |
dc.contributor.author | McGrier, Psaras L. | ko |
dc.contributor.author | Furukawa, Hiroyasu | ko |
dc.contributor.author | Cascio, Duilio | ko |
dc.contributor.author | Stoddart, J. Fraser | ko |
dc.contributor.author | Yaghi, Omar M. | ko |
dc.date.accessioned | 2013-03-12T01:49:52Z | - |
dc.date.available | 2013-03-12T01:49:52Z | - |
dc.date.created | 2012-09-27 | - |
dc.date.created | 2012-09-27 | - |
dc.date.issued | 2012 | - |
dc.identifier.citation | INORGANIC CHEMISTRY, v.51, no.12, pp.6443 - 6445 | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.uri | http://hdl.handle.net/10203/101006 | - |
dc.description.abstract | Three new metal organic frameworks [MOF-525, Zr6O4(OH)(4)(TCPP-H-2)(3); MOF-535, Zr6O4(OH)(4)(XF)(3); MOF-545, Zr6O8(H2O)(8)(TCPP-H-2)(2), where porphyrin H-4-TCPP-H-2 = (C48H24O8N4) and cruciform H-4-XF = (C42O8H22)] based on two new topologies, ftw and csq, have been synthesized and structurally characterized. MOF-525 and -535 are composed of Zr6O4(OH)(4) cuboctahedral units linked by either porphyrin (MOF-525) or cruciform (MOF-535). Another zirconium-containing unit, Zr6O8(H2O)(8), is linked by porphyrin to give the MOF-545 structure. The structure of MOF-525 was obtained by analysis of powder X-ray diffraction data. The structures of MOF-535 and -545 were resolved from synchrotron single-crystal data. MOF-525, -535, and -545 have Brunauer-Emmett-Teller surface areas of 2620, 1120, and 2260 m(2)/g, respectively. In addition to their large surface areas, both porphyrin-containing MOFs are exceptionally chemically stable, maintaining their structures under aqueous and organic conditions. MOF-525 and -545 were metalated with iron(III) and copper(II) to yield the metalated analogues without losing their high surface area and chemical stability. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal-Organic Frameworks | - |
dc.type | Article | - |
dc.identifier.wosid | 000305314500007 | - |
dc.identifier.scopusid | 2-s2.0-84862585461 | - |
dc.type.rims | ART | - |
dc.citation.volume | 51 | - |
dc.citation.issue | 12 | - |
dc.citation.beginningpage | 6443 | - |
dc.citation.endingpage | 6445 | - |
dc.citation.publicationname | INORGANIC CHEMISTRY | - |
dc.identifier.doi | 10.1021/ic300825s | - |
dc.contributor.nonIdAuthor | Morris, William | - |
dc.contributor.nonIdAuthor | Volosskiy, Boris | - |
dc.contributor.nonIdAuthor | Demir, Selcuk | - |
dc.contributor.nonIdAuthor | Gandara, Felipe | - |
dc.contributor.nonIdAuthor | McGrier, Psaras L. | - |
dc.contributor.nonIdAuthor | Furukawa, Hiroyasu | - |
dc.contributor.nonIdAuthor | Cascio, Duilio | - |
dc.type.journalArticle | Article | - |
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