Spectroscopy Identification and Thermodynamic Stability of tert-Butyl Nitrite and Methane Clathrate Hydrate

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dc.contributor.authorSung, Bo-Ramko
dc.contributor.authorShin, Kyu-Chulko
dc.contributor.authorCha, Min-Junko
dc.contributor.authorChoi, Suk-Jeongko
dc.contributor.authorLee, Jae-Hyoungko
dc.contributor.authorSeo, Yong-Wonko
dc.contributor.authorLee, Huenko
dc.date.accessioned2013-03-09T16:21:02Z-
dc.date.available2013-03-09T16:21:02Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2010-12-
dc.identifier.citationJOURNAL OF CHEMICAL AND ENGINEERING DATA, v.55, no.12, pp.5906 - 5909-
dc.identifier.issn0021-9568-
dc.identifier.urihttp://hdl.handle.net/10203/96846-
dc.description.abstractStructure-H hydrate has been highlighted due to its higher gas storage capacity and favorable thermal stability. Here, we introduce a new structure-H hydrate former, tert-butyl nitrite, and identify it through spectroscopic analysis. The hydrate structure and guest distribution were examined by using powder X-ray diffraction, Raman spectroscopy, and solid-state high-power decoupling (13)C NMR spectroscopy. The phase equilibria (L(w) + H + L(g) + V) of tert-butyl nitrite + CH(4) hydrate were measured at pressures from (3 to 4.5) MPa and at temperatures from (277 to 282) K. We also investigated the kinetic behavior of this new high-polarity hydrate former.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectPHASE-EQUILIBRIUM-
dc.titleSpectroscopy Identification and Thermodynamic Stability of tert-Butyl Nitrite and Methane Clathrate Hydrate-
dc.typeArticle-
dc.identifier.wosid000285216300081-
dc.identifier.scopusid2-s2.0-78650296394-
dc.type.rimsART-
dc.citation.volume55-
dc.citation.issue12-
dc.citation.beginningpage5906-
dc.citation.endingpage5909-
dc.citation.publicationnameJOURNAL OF CHEMICAL AND ENGINEERING DATA-
dc.identifier.doi10.1021/je100966g-
dc.contributor.localauthorLee, Huen-
dc.contributor.nonIdAuthorLee, Jae-Hyoung-
dc.contributor.nonIdAuthorSeo, Yong-Won-
dc.type.journalArticleArticle-
dc.subject.keywordPlusPHASE-EQUILIBRIUM-
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CBE-Journal Papers(저널논문)
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