Spectroscopy Identification and Thermodynamic Stability of tert-Butyl Nitrite and Methane Clathrate Hydrate

Cited 2 time in webofscience Cited 0 time in scopus
  • Hit : 207
  • Download : 0
Structure-H hydrate has been highlighted due to its higher gas storage capacity and favorable thermal stability. Here, we introduce a new structure-H hydrate former, tert-butyl nitrite, and identify it through spectroscopic analysis. The hydrate structure and guest distribution were examined by using powder X-ray diffraction, Raman spectroscopy, and solid-state high-power decoupling (13)C NMR spectroscopy. The phase equilibria (L(w) + H + L(g) + V) of tert-butyl nitrite + CH(4) hydrate were measured at pressures from (3 to 4.5) MPa and at temperatures from (277 to 282) K. We also investigated the kinetic behavior of this new high-polarity hydrate former.
Publisher
AMER CHEMICAL SOC
Issue Date
2010-12
Language
English
Article Type
Article
Keywords

PHASE-EQUILIBRIUM

Citation

JOURNAL OF CHEMICAL AND ENGINEERING DATA, v.55, no.12, pp.5906 - 5909

ISSN
0021-9568
DOI
10.1021/je100966g
URI
http://hdl.handle.net/10203/96846
Appears in Collection
CBE-Journal Papers(저널논문)
Files in This Item
There are no files associated with this item.
This item is cited by other documents in WoS
⊙ Detail Information in WoSⓡ Click to see webofscience_button
⊙ Cited 2 items in WoS Click to see citing articles in records_button

qr_code

  • mendeley

    citeulike


rss_1.0 rss_2.0 atom_1.0