Isoreticular Expansion of Metal-Organic Frameworks with Triangular and Square Building Units and the Lowest Calculated Density for Porous Crystals

Cited 173 time in webofscience Cited 0 time in scopus
  • Hit : 247
  • Download : 0
The concept and occurrence of isoreticular (same topology) series of metal organic frameworks (MOFs) is reviewed. We describe the preparation, characterization, and crystal structures of three new MOFs that are isoreticular expansions of known materials with the tbo (Cu(3)(4,4',4 ''-(benzene-1,3,5-triyl-tris(benzene-4,1-diy1))tribenzoate)(2), MO F-399) and pto topologies (Cu(3)(4,4',4 ''-(benzene-1,3,5-triyltribenzoate)(2), MOF-143; Cu(3)(4,4',4 ''-(triazine-2,4,6-triyl-tris-(benzene-4,1-diyl))tribenzoate)(2), MOF-388). One of these materials (MOF-399) has a unit cell volume 17 times larger than that of the first reported material isoreticular to it, and has the highest porosity (94%) and lowest density (0.126 g cm(-3)) of any MOFs reported to date.
Publisher
AMER CHEMICAL SOC
Issue Date
2011-09
Language
English
Article Type
Article
Keywords

HIGH H-2 ADSORPTION; RETICULAR SYNTHESIS; HYDROGEN STORAGE; PORE-SIZE; NETS; COORDINATION; SURFACE; DESIGN; SITES; FUNCTIONALITY

Citation

INORGANIC CHEMISTRY, v.50, no.18, pp.9147 - 9152

ISSN
0020-1669
URI
http://hdl.handle.net/10203/96005
Appears in Collection
Files in This Item
There are no files associated with this item.
This item is cited by other documents in WoS
⊙ Detail Information in WoSⓡ Click to see webofscience_button
⊙ Cited 173 items in WoS Click to see citing articles in records_button

qr_code

  • mendeley

    citeulike


rss_1.0 rss_2.0 atom_1.0