Radical Cyanation of Alkyl Iodides with Diethylphosphoryl Cyanide

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The beta-elimination of an organophosphoryl group from an iminyl radical is observed for the first time. On the basis of this finding, radical cyanation of alkyl iodides is achieved by using diethylphosphoryl cyanide.
Publisher
GEORG THIEME VERLAG KG
Issue Date
2009-01
Language
English
Article Type
Article
Keywords

INTRAMOLECULAR ACYLATION APPROACH; CARBON BOND FORMATION; BETA-ELIMINATION; ACYLPHOSPHONATE DERIVATIVES; CYCLIZATION REACTIONS; HYPOPHOSPHOROUS ACID; PHOSPHONATE GROUP; SULFONYL AZIDES; NITROGEN BONDS; TIN

Citation

SYNLETT, no.1, pp.81 - 84

ISSN
0936-5214
DOI
10.1055/s-0028-1087385
URI
http://hdl.handle.net/10203/95595
Appears in Collection
CH-Journal Papers(저널논문)
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