Crystal engineering by eliminating weak hydrogen bonding sites in phenolic polyene nonlinear optical crystals

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A new acentric polyene crystal OH3 with a large macroscopic second-order optical nonlinearity with optimal chromophore orientation for electro-optics and THz-wave applications has been developed by crystal engineering, eliminating weak CH center dot center dot center dot NC hydrogen-bonding sites, but still retaining strong OH center dot center dot center dot NC hydrogen-bonding sites of the analogue OH1 crystals.
Publisher
ROYAL SOC CHEMISTRY
Issue Date
2009
Language
English
Article Type
Article
Keywords

CONFIGURATIONALLY LOCKED POLYENE; INTERMOLECULAR INTERACTIONS; APPROXIMATION; SALTS

Citation

CRYSTENGCOMM, v.11, no.8, pp.1541 - 1544

ISSN
1466-8033
DOI
10.1039/b904688g
URI
http://hdl.handle.net/10203/95296
Appears in Collection
CH-Journal Papers(저널논문)
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