Intrinsic lifetimes of the Soret bands of the free-base tetraphenylporphine (H(2)TPP) and Cu(II)TPP in the condensed phase
Soret band lifetimes of the free-base tetraphenylporphine (H2TPP) and Cu(II)tetraphenylporphine ((CuTPP)-T-II) at 408 nm have been directly measured with femtosecond (fs) resolution using the fluorescence-upconversion technique for the first time, giving tau = 68 +/- 15 and 63 +/- 15 fs, respectively, in benzene solvent.
- Publisher
- ROYAL SOC CHEMISTRY
- Issue Date
- 2010
- Language
- English
- Article Type
- Article
- Keywords
RESONANCE RAMAN-SPECTRA; ELECTRON-TRANSFER; ZN-TETRAPHENYLPORPHYRIN; ULTRAFAST DYNAMICS; NICKEL PORPHYRINS; ENERGY; METALLOPORPHYRINS; SPECTROSCOPY; TEMPERATURE; COMPLEXES
- Citation
CHEMICAL COMMUNICATIONS, v.46, no.30, pp.5572 - 5574
- ISSN
- 1359-7345
- Appears in Collection
- CH-Journal Papers(저널논문)
- Files in This Item
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