Enantioselective radical addition reactions to imines using binaphthol-derived chiral N-triflyl phosphoramides

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Binaphthol-derived chiral phosphoric acid catalysts were applied to enantioselective radical addition reactions of imines and provided chiral amines with good enantioselectivities (73-84% ee). Furthermore,, the enantioselectivities were not affected by either electronic properties of phenyl imines or radical precursors. (C) 2009 Elsevier Ltd. All rights reserved.
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Issue Date
2009-07
Language
English
Article Type
Article
Keywords

BRONSTED ACID CATALYSIS; MANNICH-TYPE REACTION; TRANSFER HYDROGENATION; ASYMMETRIC CATALYSIS; BOND DONORS; ALKYLATION; INDOLES

Citation

TETRAHEDRON LETTERS, v.50, no.26, pp.3345 - 3348

ISSN
0040-4039
DOI
10.1016/j.tetlet.2009.02.136
URI
http://hdl.handle.net/10203/94976
Appears in Collection
CH-Journal Papers(저널논문)
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