Enantioselective radical addition reactions to imines using binaphthol-derived chiral N-triflyl phosphoramides
Binaphthol-derived chiral phosphoric acid catalysts were applied to enantioselective radical addition reactions of imines and provided chiral amines with good enantioselectivities (73-84% ee). Furthermore,, the enantioselectivities were not affected by either electronic properties of phenyl imines or radical precursors. (C) 2009 Elsevier Ltd. All rights reserved.
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
- Issue Date
- 2009-07
- Language
- English
- Article Type
- Article
- Keywords
BRONSTED ACID CATALYSIS; MANNICH-TYPE REACTION; TRANSFER HYDROGENATION; ASYMMETRIC CATALYSIS; BOND DONORS; ALKYLATION; INDOLES
- Citation
TETRAHEDRON LETTERS, v.50, no.26, pp.3345 - 3348
- ISSN
- 0040-4039
- Appears in Collection
- CH-Journal Papers(저널논문)
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