Destruction of CFC113 in supercritical and subcritical water

Destruction of 1,1,2-trichlorotrifluoroethane (CFC113) in supercritical and subcritical water was performed over a wide range of pressure at 673 K. The hydrolysis reaction of CFC113 in the supercritical water could lead to complete destruction of CFC113, while the CFC113 destruction below the critical pressure of water was quite low. The Cl- destruction yields were higher than those of F over the whole pressure range including both supercritical and subcritical regions, which implies that the bonding energy of F on the backbone of CFC113 is stronger than that of Cl. The destruction yields represented by two ions were found to have the linear dependency on the reduced water density.
Publisher
KOREAN INST CHEM ENGINEERS
Issue Date
1996-11
Language
ENG
Keywords

OXIDATION; KINETICS; HYDROLYSIS; MIXTURES; AMMONIA

Citation

KOREAN JOURNAL OF CHEMICAL ENGINEERING, v.13, no.6, pp.640 - 641

ISSN
0256-1115
URI
http://hdl.handle.net/10203/9479
Appears in Collection
CBE-Journal Papers(저널논문)
  • Hit : 180
  • Download : 1
  • Cited 0 times in thomson ci
This item is cited by other documents in WoS
⊙ Detail Information in WoSⓡClick to seewebofscience_button
⊙ Cited 7 items in WoSClick to see citing articles inrecords_button

qr_code

  • mendeley

    citeulike


rss_1.0 rss_2.0 atom_1.0