Anionic Cyclization of N-(trans-2,3-Diphenylaziridin-1-yl)imines: Its Application to Sesquiterpene Synthesis via Consecutive Carbon-Carbon Bond-Formation Approach

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The anionic consecutive carbon-carbon (CC-C) bond formation can be achieved by the anionic cyclizations of N-(trans-2,3-diphenylaziridin-1-yl)imines with alkyllithiums. The synthetic efficiency of CC-C bond-formation approach has been demonstrated in the synthesis of dl-pentalenene and dl-cedrone.
Publisher
Georg Thieme Verlag Kg
Issue Date
2010-06
Language
English
Article Type
Article
Keywords

N-AZIRIDINYL IMINES; TANDEM RADICAL CYCLIZATION; EFFICIENT SYNTHESIS; BETA-CEDRENE; ROUTE; ALKYLLITHIUMS; PENTALENENE; STEREOCHEMISTRY; DERIVATIVES; ACETYLENES

Citation

SYNLETT, no.10, pp.1511 - 1514

ISSN
0936-5214
DOI
10.1055/s-0029-1219933
URI
http://hdl.handle.net/10203/94004
Appears in Collection
CH-Journal Papers(저널논문)
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