Total Synthesis of (-)-13-Acetoxymodhephene and (+)-14-Acetoxymodhephene

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Stereoselective epoxidation of [4.3.3]propellane 16 set the stage for the Lewis acid catalyzed stereospecific ring contraction to an oxygenated modhephene structure and eventually led to the total synthesis of (-)-13-acetoxymodhephene and (+)-14-acetoxyrnodhephene. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
Publisher
WILEY-V C H VERLAG GMBH
Issue Date
2009-10
Language
English
Article Type
Article
Keywords

ENANTIOSELECTIVE SYNTHESIS; ABSOLUTE-CONFIGURATION; OPTICAL RESOLUTION; MODHEPHENE; SESQUITERPENES; ALCOHOLS; REAGENT; KETONES; (+/-)-MODHEPHENE; (-)-MODHEPHENE

Citation

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, no.29, pp.5028 - 5037

ISSN
1434-193X
DOI
10.1002/ejoc.200900713
URI
http://hdl.handle.net/10203/93980
Appears in Collection
CH-Journal Papers(저널논문)
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