Selective catalytic activity of ball-shaped Pd@MCM-48 nanocatalysts

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Remarkable selectivity is achieved in the cleavage of benzyl ethers using ball-shaped palladium nanocatalysts, Pd@MCM-48, in an MCM-48 matrix. The unique nanocatalysts not only feature unprecedented complete hydrogenolysis selectivity of a benzyl ether over hydrogenation of a double bond, but also demonstrate selective cleavage of unsubstituted benzyl ether over substituted benzyl ethers.
Publisher
ROYAL SOC CHEMISTRY
Issue Date
2006
Language
English
Article Type
Article
Keywords

MESOPOROUS SILICA; PALLADIUM; HYDROGENATION; NANOPARTICLES; HYDROGENOLYSIS; EFFICIENT

Citation

CHEMICAL COMMUNICATIONS, no.12, pp.1325 - 1327

ISSN
1359-7345
DOI
10.1039/b517082f
URI
http://hdl.handle.net/10203/91012
Appears in Collection
CH-Journal Papers(저널논문)
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