Stereofacial control in asymmetric cyanosilylation of aldehydes catalyzed by novel S-proline-derived titanium complexes
Asymmetric cyanosilylation of aryl aldehydes has been achieved utilizing catalytic amounts of novel chiral ligands. Chiral ligands of amino alcohols and aminophosphine gave S-configured cyanosilylated products with up to 84% ee. In contrast, C-2-symmetric ligands resulted in R-configured products with up to 95% ee.
- Publisher
- GEORG THIEME VERLAG KG
- Issue Date
- 2005-08
- Language
- English
- Article Type
- Article
- Keywords
OPTICALLY-ACTIVE CYANOHYDRINS; CHIRAL OXAZABOROLIDINIUM ION; ENANTIOSELECTIVE CYANOSILYLATION; STEREOSELECTIVE-SYNTHESIS; CHEMOENZYMATIC SYNTHESIS; SYNTHETIC APPLICATIONS; AMINO-ACIDS; INHIBITORS; CONVERSION; EPHEDRINE
- Citation
SYNLETT, v.13, pp.1995 - 1998
- ISSN
- 0936-5214
- Appears in Collection
- CH-Journal Papers(저널논문)
- Files in This Item
- There are no files associated with this item.
This item is cited by other documents in WoS
| ⊙ Detail Information in WoSⓡ | Click to see |  |
| ⊙ Cited 13 items in WoS | Click to see citing articles in |  |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.