Titanatranes containing tetradentate ligands with controlled steric hindrance
New monomeric titanatranes [GRAPHICS] (Ar = 2,6-di-i-Pr-phenyl; x = 0, 5; x = 1, 6; x = 2, 7; x = 3, 8) were synthesized from the corresponding tetradentate ligands 1-4, respectively, using an equimolar mixture of Ti(O-i-Pr)4 and 2,6-di-i-Pr-phenol. These compounds show the catalytic activity for the ring opening polymerization of I-lactide. (c) 2007 Elsevier B.V. All rights reserved.
- Publisher
- ELSEVIER SCIENCE SA
- Issue Date
- 2007-07
- Language
- English
- Article Type
- Article
- Keywords
RING-OPENING POLYMERIZATION; LACTIDE POLYMERIZATION; CYCLIC ESTERS; ZIRCONIUM COMPLEXES; TITANIUM COMPLEXES; INITIATORS; CATALYST; ALKOXIDE; AZATITANATRANES; REACTIVITY
- Citation
JOURNAL OF ORGANOMETALLIC CHEMISTRY, v.692, no.16, pp.3519 - 3525
- ISSN
- 0022-328X
- Appears in Collection
- CH-Journal Papers(저널논문)
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