Clathrate phase equilibria for the water plus deuterium oxide plus carbon dioxide and water plus deuterium oxide plus chlorodifluoromethane (R22) systems

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Clathrate phase equilibria for two ternary water + deuterium oxide + carbon dioxide and water + deuterium oxide + chlorodifluoromethane (R22) systems were measured at several different mass % of water and deuterium oxide mixtures. Equilibrium dissociation pressures of these two ternary systems at the three-phase (clathrate-liquid-vapor) boundaries range (1.43 to 4.86) MPa and (0.141 to 0.886) MPa, respectively. The temperature range occupied by the three-phase boundary of the water + deuterium oxide + R22 system is a little larger than that of the water + deuterium oxide + carbon dioxide system. The dissociation pressures at the quadruple points were found to steadily increase with deuterium oxide composition.
Publisher
AMER CHEMICAL SOC
Issue Date
1996-09
Language
English
Article Type
Article
Citation

JOURNAL OF CHEMICAL AND ENGINEERING DATA , v.41, no.5, pp.1114 - 1116

ISSN
0021-9568
URI
http://hdl.handle.net/10203/9017
Appears in Collection
CBE-Journal Papers(저널논문)
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