Magnetic Transition and Long-Time Relaxation Behavior Induced by Selective Injection of Guest Molecules into Clathrate Hydrates

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Magnetic molecules physisorbed into low-dimensional nanostructures of microporous materials such as graphite and metal-organic frameworks have been verified to exhibit an unusual magnetic behavior. We demonstrate that the selective injection of both magnetic and nonmagnetic guest molecules into the water-ice cages of clathrate hydrates to form a 3D superstructure with tetrahedral and diamond-like sublattices can modify the inherent magnetism.
Publisher
AMER CHEMICAL SOC
Issue Date
2009-04
Language
English
Article Type
Article
Keywords

OXYGEN; ICE

Citation

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.131, no.16, pp.5736 - 5736

ISSN
0002-7863
DOI
10.1021/ja9009088
URI
http://hdl.handle.net/10203/8867
Appears in Collection
CBE-Journal Papers(저널논문)
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