Enantioselective conjugate radical addition to alpha '-hydroxy enones

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Enantioselective conjugate radical addition to alpha '-hydroxy alpha,beta-unsaturated ketones, compounds containing bidentate donors, has been investigated. It has been found that radical additions to alpha '-hydroxy alpha,beta-unsaturated ketones in the presence of Mg(NTf2)(2) and bisoxazoline ligand 5a proceeded cleanly, yielding the addition products in high chemical yields and good enantiomeric excesses.
Publisher
Amer Chemical Soc
Issue Date
2006-09
Language
English
Article Type
Article
Keywords

CHIRAL LEWIS-ACID; CATALYSIS; ALKYLATIONS

Citation

ORGANIC LETTERS, v.8, no.19, pp.4311 - 4313

ISSN
1523-7060
DOI
10.1021/ol061634z
URI
http://hdl.handle.net/10203/87390
Appears in Collection
CH-Journal Papers(저널논문)
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