Enantioselective radical conjugate addition to alpha '-phosphoric enones

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Catalytic enantioselective radical conjugate addition reactions using alpha'-phosphoric enone templates have been studied. The C(2)-symmetric bisoxazoline-zinc(II) complex proves to be effective for high enantioselectivities and chemical yields. In addition, intermediate alpha-carbonyl alkyl radicals could be trapped with allyltributylstannane to afford anti-isomers as major products with high enantioselectivities.
Publisher
Amer Chemical Soc
Issue Date
2008-10
Language
English
Article Type
Article
Keywords

LEWIS-ACIDS; DIELS-ALDER; CATALYSIS; BIS(OXAZOLINE); COMPLEXES; FRIEDEL

Citation

ORGANIC LETTERS, v.10, no.19, pp.4255 - 4258

ISSN
1523-7060
DOI
10.1021/ol8017177
URI
http://hdl.handle.net/10203/87301
Appears in Collection
CH-Journal Papers(저널논문)
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