Enantioselective radical conjugate addition to alpha '-phosphoric enones
Catalytic enantioselective radical conjugate addition reactions using alpha'-phosphoric enone templates have been studied. The C(2)-symmetric bisoxazoline-zinc(II) complex proves to be effective for high enantioselectivities and chemical yields. In addition, intermediate alpha-carbonyl alkyl radicals could be trapped with allyltributylstannane to afford anti-isomers as major products with high enantioselectivities.
- Publisher
- Amer Chemical Soc
- Issue Date
- 2008-10
- Language
- English
- Article Type
- Article
- Keywords
LEWIS-ACIDS; DIELS-ALDER; CATALYSIS; BIS(OXAZOLINE); COMPLEXES; FRIEDEL
- Citation
ORGANIC LETTERS, v.10, no.19, pp.4255 - 4258
- ISSN
- 1523-7060
- Appears in Collection
- CH-Journal Papers(저널논문)
- Files in This Item
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