Tin-free, radical-mediated gamma-alkylations of alpha,beta-unsaturated esters via O-tert-alkyl dienol ethers

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Tin-free, radical-mediated gamma-alkylation of alpha,beta-unsaturated esters is accomplished by radical addition and beta-fragmentation of O-tert-alkyl dienol ethers and subsequent iodine atom transfer process.
Publisher
Georg Thieme Verlag Kg
Issue Date
2008-01
Language
English
Article Type
Article
Keywords

TRANSFER ADDITION-REACTIONS; REGIOSELECTIVE CONTROL ELEMENTS; CARBON BOND FORMATION; 1,2-ASYMMETRIC INDUCTION; FRAGMENTATION REACTIONS; ACYLATION REACTIONS; ALLYL SULFONES; KETONES; IODINE; ACIDS

Citation

SYNLETT, no.1, pp.49 - 54

ISSN
0936-5214
DOI
10.1055/s-2007-992385
URI
http://hdl.handle.net/10203/86876
Appears in Collection
CH-Journal Papers(저널논문)
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