FEMTOCHEMISTRY OF ORGANOMETALLICS - DYNAMICS OF METAL-METAL AND METAL-LIGAND BOND-CLEAVAGE IN M(2)(CO)(10)
We report femtochemical studies of the organometallic dimetal decacarbonyl. By the use of mass spectrometry, we obtain the temporal dynamics in the channels for metal-metal and metal-ligand bond cleavage. The time scale observed for cleavage and for structural bridging indicates the nature of the repulsion along the two reaction coordinates and the interplay between the bond order and the femtosecond dynamics.
- Publisher
- ELSEVIER SCIENCE BV
- Issue Date
- 1995-02
- Language
- English
- Article Type
- Article
- Keywords
GAS-PHASE MN2(CO)10; MANGANESE DECACARBONYL; PHOTO-DISSOCIATION; PHOTOCHEMISTRY; PHOTODISSOCIATION; PHOTOFRAGMENTATION; IONIZATION; CARBONYLS; COMPLEXES; RESONANCE
- Citation
CHEMICAL PHYSICS LETTERS, v.233, no.5-6, pp.500 - 508
- ISSN
- 0009-2614
- Appears in Collection
- CH-Journal Papers(저널논문)
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