HIGHLY DIASTEREOSELECTIVE ADDITION OF ORGANOMETALLICS TO NOVEL CHIRAL ALPHA-KETOAMIDES OF (S)-2-METHOXYMETHYLINDOLINE

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The stereocontrolled nucleophilic addition of organametallics to novel chiral alpha-ketoamides which were synthesized from (S)-2-methoxymethylindoline as a chiral auxiliary was carried out to obtain alpha-hydroxyamides with extremely high diastereoselectivities ( up to dr greater than or equal to 99:1).
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Issue Date
1995-05
Language
English
Article Type
Note
Keywords

ASYMMETRIC-SYNTHESIS; KETO AMIDES; AMINO ACIDS; REDUCTION; ALCOHOLS; ESTERS

Citation

TETRAHEDRON-ASYMMETRY, v.6, no.5, pp.1025 - 1026

ISSN
0957-4166
DOI
10.1016/0957-4166(95)00115-6
URI
http://hdl.handle.net/10203/72312
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