HIGHLY DIASTEREOSELECTIVE ADDITION OF ORGANOMETALLICS TO NOVEL CHIRAL ALPHA-KETOAMIDES OF (S)-2-METHOXYMETHYLINDOLINE
The stereocontrolled nucleophilic addition of organametallics to novel chiral alpha-ketoamides which were synthesized from (S)-2-methoxymethylindoline as a chiral auxiliary was carried out to obtain alpha-hydroxyamides with extremely high diastereoselectivities ( up to dr greater than or equal to 99:1).
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
- Issue Date
- 1995-05
- Language
- English
- Article Type
- Note
- Keywords
ASYMMETRIC-SYNTHESIS; KETO AMIDES; AMINO ACIDS; REDUCTION; ALCOHOLS; ESTERS
- Citation
TETRAHEDRON-ASYMMETRY, v.6, no.5, pp.1025 - 1026
- ISSN
- 0957-4166
- Appears in Collection
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