FACILE SYNTHESIS OF BETA-KETOESTERS MEDIATED BY SMI2 - REFORMATSKY REACTION TYPE SELFCONDENSATION

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alpha-Bromoesters are converted to beta-ketoesters by treatment with samarium diiodide via self condensation under the mild conditions. The reaction appears to be initiated via the formation of samarium diiodide ester enolate for the Reformatsky reation type.
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Issue Date
1995-03
Language
English
Article Type
Article
Keywords

ESTERS; ROUTE

Citation

TETRAHEDRON LETTERS, v.36, no.10, pp.1673 - 1674

ISSN
0040-4039
DOI
10.1016/0040-4039(95)00127-X
URI
http://hdl.handle.net/10203/71565
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