Effects of intercalation-induced stress on lithium transport through porous LiCoO2 electrode

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The lithium transport through inter-and intra-particles in porous Li1-deltaCoO2 electrode was investigated in I M LiClO4 propylene carbonate (PC) solution by using electrochemical impedance spectroscopy (EIS) combined with cyclic voltammetry. The measured contact resistance and the lithium ion diffusivity were discussed as functions of the lithium content (1 - delta) and oxide particle size in terms of the lithium intercalation-induced stress.
Publisher
ELSEVIER SCIENCE BV
Issue Date
1997
Language
ENG
Article Type
Article
Keywords

VANADIUM-OXIDE ELECTRODE; NONAQUEOUS CELL; AC-IMPEDANCE; BATTERIES; ELECTROCHEMISTRY; LIXCOO2; DIOXIDE

Citation

SOLID STATE IONICS, v.99, pp.173 - 183

ISSN
0167-2738
DOI
10.1016/S0167-2738(97)00253-1
URI
http://hdl.handle.net/10203/69777
Appears in Collection
MS-Journal Papers(저널논문)
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