Reaction of Pummerer Rearrangement Intermediate with Thiols: New Synthetic Method of S,S-Thioacetals of Formylphosphonate

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Pummerer rearrangement reaction intermediate 2) of phenylsulfinyl methanephosphonate(1) has been found to react mildly with thiols(3) in the presence of stannic chloride to provide S,S-thioacetals of formylphosphonate(4).
Publisher
Taylor & Francis Inc
Issue Date
1994
Language
ENG
Article Type
Article
Keywords

CARBANIONS

Citation

SYNTHETIC COMMUNICATIONS, v.24, no.16, pp.2313 - 2318

ISSN
0039-7911
URI
http://hdl.handle.net/10203/65442
Appears in Collection
RIMS Journal Papers
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