Generation of Alkylidene Carbenes from α, β-Epoxy-N-aziridinyl Imines. A New Route to Cyclopentenols

Thermal reaction of alpha,beta-epoxy-N-aziridinyl imines in refluxing toluene would initially generate the reactive alkylidene carbenes which underwent intramolecular carbon-hydrogen insertion reactions to afford cyclopentenols.
Publisher
Pergamon-Elsevier Science Ltd
Issue Date
1994-11
Language
ENG
Keywords

N-AZIRIDINYL IMINES; UNSATURATED CARBENES; HYPERVALENT ALKENYLIODONIUM; ACETYLENIC ESTERS; ALPHA-ELIMINATION; ALKYNYL; REARRANGEMENT; CYCLIZATION; CARBON; SALTS

Citation

TETRAHEDRON LETTERS, v.35, no.45, pp.8405 - 8407

ISSN
0040-4039
URI
http://hdl.handle.net/10203/60057
Appears in Collection
CH-Journal Papers(저널논문)
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