A neutral group 4 poly(methylmethacrylate) catalyst derived from ortho-carborane

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rac-Zr(eta(5):eta(1)-CpCMe2CB10H10C)(2), prepared from the reaction of the dilithium salt of the new isopropyl-bridged cyclopentadienyl o-carboranyl ligand CpHCMe2CB10H10CH with ZrCl4 catalyzes the formation of syndiotactic poly(methyl methacrylate) ill THF in the absence of any alkylating reagent or cationic center generator.
Publisher
AMER CHEMICAL SOC
Issue Date
1998-07
Language
English
Article Type
Article
Keywords

MOLECULAR-WEIGHT POLYMERS; METHYL-METHACRYLATE; LIVING POLYMERIZATIONS; UNIQUE CATALYSIS; COMPLEXES; COPOLYMERIZATIONS; INITIATORS; LACTONES; ROUTE

Citation

ORGANOMETALLICS, v.17, no.14, pp.2933 - 2935

ISSN
0276-7333
URI
http://hdl.handle.net/10203/3632
Appears in Collection
CH-Journal Papers(저널논문)
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