Novel monodentate phosphine modified Pd(acac)(2)/BF3OEt2 catalyst system for the synthesis of poly(5-alkyl-2-norbornene)s

Pd(acac)(2) + 2PPh(3) + 25BF(3)OEt(2) catalyst system has been employed for the polymerization of 5-alkyl-2-norbornenes. The activity of the catalyst system is comparable to that of most active late transition metal catalysts described in the literature. The introduction of a phosphine to the system switched the carbocationic polymerization mechanism to the coordination Ziegler-Natta polymerization. © 2005 Elsevier B.V. All rights reserved.
Publisher
Elsevier Science Bv
Issue Date
2005
Language
ENG
Keywords

IN-SITU FORMATION; ADDITION POLYMERIZATION; NORBORNENE DERIVATIVES; VINYL-POLYMERIZATION; FUNCTIONAL-GROUPS; METAL-CATALYSTS; PRE-CATALYSTS; COMPLEXES; HOMOPOLYMERIZATION; COPOLYMERIZATION

Citation

CATALYSIS COMMUNICATIONS, v.6, no.5, pp.337 - 342

ISSN
1566-7367
DOI
10.1016/j.catcom.2005.02.007
URI
http://hdl.handle.net/10203/3600
Appears in Collection
CBE-Journal Papers(저널논문)
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