Synthesis of vinyl tellurides using new organotellurium reagent, tellurophosphonate = 새로운 유기텔루리움 시약인 텔루로포스포네이트를 이용한 비닐 텔루라이드의 합성

The first preparation of tellurophosphonates has been studied and vinyl tellurides were synthesized by the Wittig-Horner reaction of tellurophosphonates with aldehydes. Reaction of the lithio anions derived from diethyl alkylphosphonates with phenyltellurenyl iodide gave the diethyl phenyltelluroalkylphosphonate. Tellurophosphonates were also prepared by the reaction of lithium tellurolates with iodomethylphosphonate. Vinyl tellurides can be synthesized by the treatment of a mixture of the tellurophosphonate and of the carbonyl compound with NaH in boiling THF.
Advisors
Oh, Dong-Youngresearcher오동영researcher
Publisher
한국과학기술원
Issue Date
1993
Identifier
68373/325007 / 000911476
Language
eng
Description

학위논문(석사) - 한국과학기술원 : 화학과, 1993.2, [ iii, 48 p. ]

URI
http://hdl.handle.net/10203/32643
Link
http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=68373&flag=t
Appears in Collection
CH-Theses_Master(석사논문)
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