Oxidation of organosulfur compounds using iodosobenzene = 아이오도소벤젠을 이용한 유기황화합물들의 산화반응

It was found that various thioacetals and thioketals readily reacted with iodosobenzene under mild conditions in methanol to afford the corresponding parent carbonyl compounds in excellent yiels. [Hydroxy(benzeneseleninyloxy)iodo] benzene($\underline{1}$) as a newtrivalent iodine oxidant was prepared and confirmed by its mp, $^1HNMR$, IR, and elemental analysis. Various sulfides were realted with this new oxident to give correponding sulfoxides without formation of sulfones. It was found that various o-nitrophenyl benzene-sulfonamides were prepared form the reaction of benzofuroxans and arylsulfinates under reflux in aqueous acetonitrile in good yields.
Advisors
Kim, Yong-Haeresearcher김용해researcher
Publisher
한국과학기술원
Issue Date
1991
Identifier
67623/325007 / 000891129
Language
eng
Description

학위논문(석사) - 한국과학기술원 : 화학과, 1991.2, [ iv, 46 p. ]

URI
http://hdl.handle.net/10203/32593
Link
http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=67623&flag=t
Appears in Collection
CH-Theses_Master(석사논문)
Files in This Item
There are no files associated with this item.
  • Hit : 53
  • Download : 0
  • Cited 0 times in thomson ci

qr_code

  • mendeley

    citeulike


rss_1.0 rss_2.0 atom_1.0