Oxidation of organosulfur compounds using iodosobenzene = 아이오도소벤젠을 이용한 유기황화합물들의 산화반응

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It was found that various thioacetals and thioketals readily reacted with iodosobenzene under mild conditions in methanol to afford the corresponding parent carbonyl compounds in excellent yiels. [Hydroxy(benzeneseleninyloxy)iodo] benzene($\underline{1}$) as a newtrivalent iodine oxidant was prepared and confirmed by its mp, $^1HNMR$, IR, and elemental analysis. Various sulfides were realted with this new oxident to give correponding sulfoxides without formation of sulfones. It was found that various o-nitrophenyl benzene-sulfonamides were prepared form the reaction of benzofuroxans and arylsulfinates under reflux in aqueous acetonitrile in good yields.
Advisors
Kim, Yong-Haeresearcher김용해researcher
Description
한국과학기술원 : 화학과,
Publisher
한국과학기술원
Issue Date
1991
Identifier
67623/325007 / 000891129
Language
eng
Description

학위논문(석사) - 한국과학기술원 : 화학과, 1991.2, [ iv, 46 p. ]

URI
http://hdl.handle.net/10203/32593
Link
http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=67623&flag=dissertation
Appears in Collection
CH-Theses_Master(석사논문)
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