Novel derivative chemistry of silatranes = 새로운 실라트란의 유도체 화학

In order to synthesize heteropolynuclear comounds containing bonding interaction between the silicon of silatrane and M (M: transition metal or main group element), a series of reactions such as HCl elimination, salt elimination reaction, and oxidative addition reaction has been utilized. The reaction of $Tl_2C_2B_9H_{11}$ with 1-bromosilatrane in tetrahydrofuran gives tetrasilatranyloxysilane having novel structure, which is characterized by a single-crystal x-ray diffraction study. The reaction of $SnBr_2$ with 1-bromosilatrane in acetonitrile gives the mixture of yellow and white solid, which was isolated and characterized by $^1H-NMR$, $^{29}Si-NMR$, $^{119}Sn-NMR$ and Mass spectroscopy. The yellow compound was characterized as tribromo-1 silatranyltin which had Si-Sn bonding interaction.
Advisors
Do, Young-Kyuresearcher도영규researcher
Publisher
한국과학기술원
Issue Date
1990
Identifier
67098/325007 / 000881244
Language
eng
Description

학위논문(석사) - 한국과학기술원 : 화학과, 1990.2, [ iv, 47 p. ]

URI
http://hdl.handle.net/10203/32569
Link
http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=67098&flag=t
Appears in Collection
CH-Theses_Master(석사논문)
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