(The) reactions of 1-alkoxy vinyl phosphonium salts = 1-알콕시 비닐 포스핀 염을 이용한 반응

1-Alkoxy vinyl phosphonium salt is reacted with sodium salts of 1,3diketones or $\beta$ -ketoesters to give substituted 2, 3-dihydrofurans. It also reacted with diethyl-(2-phenyl-2-oxo) ethyl malonate to produce substituted cyclopentenes. And the applicability of 1-alkoxy vinyl phosphonium salt was investigated in other various reactions including the isomerization of 1-alkoxy vinyl phosphonium salt in which an acidic proton exists at the allylic position to 1-alkoxy allyl phosphonium salt, the reaction with various organometallic reagents and intramolecular cyclization via radical process.
Advisors
Kim, Sung-Gakresearcher김성각researcher
Publisher
한국과학기술원
Issue Date
1990
Identifier
67091/325007 / 000881131
Language
eng
Description

학위논문(석사) - 한국과학기술원 : 화학과, 1990.2, [ ii, 44 p. ]

URI
http://hdl.handle.net/10203/32562
Link
http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=67091&flag=t
Appears in Collection
CH-Theses_Master(석사논문)
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