Selective cleavage of acetal-type ether using magnesium bromide = 마그네슘 브로마이드를 이용한 아세탈 타입 에테르의 선택적 절단

The synthetic utility of magnesium bromide has been investigated, and it has been found that magnesium bromide is effective for the direct conversion of MOM ethers into alkylthiomehyl ethers in the presence of appropriate nucleophiles such as thiophenol and n-butanethiol. Magnesium bromide can be used as a mild and efficient reagent for the selective cleavage of MOM and MTM ethers in the presence of MEM ethers. The selective cleavage of SEM ethers in the presence of tertbutyldimethylsilyl ethers has been also performed successfully with magnesium bromide and n-butanethiol.
Advisors
Kim, Sung-Gakresearcher김성각researcher
Publisher
한국과학기술원
Issue Date
1990
Identifier
67088/325007 / 000881034
Language
eng
Description

학위논문(석사) - 한국과학기술원 : 화학과, 1990.2, [ iv, 49 p. ]

URI
http://hdl.handle.net/10203/32559
Link
http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=67088&flag=t
Appears in Collection
CH-Theses_Master(석사논문)
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