Large-scale morphology-controlled SWCNT/polymeric microsphere arrays can be obtained by a wet chemical self-assembly technique. The loading of SWCNTs, the length of SWCNTs, and the size and nature of polymeric microspheres can easily be controlled. Similar results can also be reached using this method for MWCNTs. In both types of CNTs, they form an interesting interactive 'net' structure on spheres and sphere joints. The SWCNT/PS-modified Au electrode was used for detection of uric acid by cyclic voltammetry and single-potential time-based techniques. The preliminary results show that the modified electrode presents good sensitivity and stability to uric acid.