Ligand-Controlled Direct Hydroformylation of Trisubstituted Olefins

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The direct hydroformylation of trisubstituted olefins has been achieved with a combination of a Rh(I) catalyst and a pi-acceptor phosphorus (briphos) ligand. A sterically bulky briphos ligand with a large cone angle that forms a 1:1 complex with Rh(I) is found to be reactive for the hydroformylation of trisubstituted olefins. The aldehyde products were obtained with high diastereoselectivity (>99:1) and regioselectivity (49%-81%).
Publisher
AMER CHEMICAL SOC
Issue Date
2019-08
Language
English
Article Type
Article
Citation

ORGANIC LETTERS, v.21, no.15, pp.5789 - 5792

ISSN
1523-7060
DOI
10.1021/acs.orglett.9b01639
URI
http://hdl.handle.net/10203/266622
Appears in Collection
EEW-Journal Papers(저널논문)CH-Journal Papers(저널논문)
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