Intrinsic relation between hot electron flux and selectivity under methanol oxidation메탄올 산화반응에서 뜨거운 전자와 메틸 포르메이트 선택성의 연관성에 대한 연구

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The roles of hot electron flow and metal-oxide interfaces in catalytic activity and selectivity are important issues in heterogeneous catalysis. In spite of its importance in fundamental understanding electronic excitations on the surface, there has been no report showing the relation between the hot electron flow and catalytic selectivity. We have observed a significant increase of hot electron flux with methyl formate creation and managed to explain this phenomenon with DFT calculation. Based on these results, we introduce the intrinsic relation between methyl formate selectivity and the hot electron flux in methanol oxidation.
Advisors
Jung, Yousungresearcher정유성researcher
Description
한국과학기술원 :생명화학공학과,
Publisher
한국과학기술원
Issue Date
2019
Identifier
325007
Language
eng
Description

학위논문(석사) - 한국과학기술원 : 생명화학공학과, 2019.2,[ii, 14 p. :]

Keywords

Methanol oxidation▼ahot electron▼acatalyst▼aplatinum▼aselectivity; 메탄올 산화반응▼a뜨거운 전자▼a촉매▼a백금▼a선택성

URI
http://hdl.handle.net/10203/266390
Link
http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=843242&flag=dissertation
Appears in Collection
CBE-Theses_Master(석사논문)
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