Total Synthesis of (−)-FD-838 and (−)-Cephalimysin A
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Jo, Deokhee | ko |
| dc.contributor.author | Han, Sunkyu | ko |
| dc.date.accessioned | 2019-08-06T00:20:03Z | - |
| dc.date.available | 2019-08-06T00:20:03Z | - |
| dc.date.created | 2019-08-05 | - |
| dc.date.created | 2019-08-05 | - |
| dc.date.created | 2019-08-05 | - |
| dc.date.issued | 2019-07 | - |
| dc.identifier.citation | ORGANIC LETTERS, v.21, no.15, pp.6045 - 6049 | - |
| dc.identifier.issn | 1523-7060 | - |
| dc.identifier.uri | http://hdl.handle.net/10203/264035 | - |
| dc.description.abstract | We completed a nine-step total synthesis of (−)-FD-838 and (−)-cephalimysin A. Our synthesis features a biogenetically guided assembly of the highly oxidized spirocyclic core by Snider-type tandem epoxidations of the chiral substrate derived from an amino acid derivative. Our synthetic approach provides a general and versatile solution to access spirocyclic PKS-NRPS-based secondary fungal metabolites. | - |
| dc.language | English | - |
| dc.publisher | AMER CHEMICAL SOC | - |
| dc.title | Total Synthesis of (−)-FD-838 and (−)-Cephalimysin A | - |
| dc.type | Article | - |
| dc.identifier.wosid | 000480371600057 | - |
| dc.identifier.scopusid | 2-s2.0-85070895912 | - |
| dc.type.rims | ART | - |
| dc.citation.volume | 21 | - |
| dc.citation.issue | 15 | - |
| dc.citation.beginningpage | 6045 | - |
| dc.citation.endingpage | 6049 | - |
| dc.citation.publicationname | ORGANIC LETTERS | - |
| dc.identifier.doi | 10.1021/acs.orglett.9b02203 | - |
| dc.contributor.localauthor | Han, Sunkyu | - |
| dc.description.isOpenAccess | N | - |
| dc.type.journalArticle | Article | - |
| dc.subject.keywordPlus | ABSOLUTE-CONFIGURATION | - |
| dc.subject.keywordPlus | METABOLITE | - |
| dc.subject.keywordPlus | ANGIOGENESIS | - |
| dc.subject.keywordPlus | PSEUROTIN | - |
| dc.subject.keywordPlus | PRODUCT | - |
| dc.subject.keywordPlus | FD-838 | - |
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