Ni-Mediated Generation of "CN" Unit from Formamide and Its Catalysis in the Cyanation Reactions

Cited 0 time in webofscience Cited 0 time in scopus
  • Hit : 22
  • Download : 0
The in situ generation of a "cyano" unit from readily available organic precursors is of high interest in synthetic chemistry. Herein, we report the first example of Ni-mediated dehydration of formamide to form "CN" and its subsequent catalytic applications in the hydrocyanation of alkynes and cyanation of aryl halides. Formamide can serve as a convenient source for the nitrile unit, in that it releases water as the only byproduct.
Publisher
AMER CHEMICAL SOC
Issue Date
2019-04
Language
English
Article Type
Article
Citation

ACS CATALYSIS, v.9, no.4, pp.3360 - 3365

ISSN
2155-5435
DOI
10.1021/acscatal.8b05111
URI
http://hdl.handle.net/10203/261697
Appears in Collection
CH-Journal Papers(저널논문)
Files in This Item
There are no files associated with this item.

qr_code

  • mendeley

    citeulike


rss_1.0 rss_2.0 atom_1.0