Asymmetric formation of tert-alkylamines from serinols by a dual function catalyst

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dc.contributor.authorYou, Young Sukko
dc.contributor.authorKim, Tae Wooko
dc.contributor.authorKang, SungHoko
dc.date.accessioned2019-04-15T15:50:39Z-
dc.date.available2019-04-15T15:50:39Z-
dc.date.created2013-10-29-
dc.date.issued2013-
dc.identifier.citationCHEMICAL COMMUNICATIONS, v.49, no.83, pp.9669 - 9671-
dc.identifier.issn1359-7345-
dc.identifier.urihttp://hdl.handle.net/10203/255296-
dc.description.abstractConsecutive intramolecular desymmetrization and kinetic resolution of 2-substituted N-phenoxycarbonylserinols have been achieved in one-pot by a single chiral catalyst, bisox(7)-CuCl2, to form oxazolidinones with remarkable enantioselectivities (94-99% ee) as tert-alkylamine building blocks. The process culminates in a dual-function of the chiral catalyst.-
dc.languageEnglish-
dc.publisherROYAL SOC CHEMISTRY-
dc.subjectQUATERNARY CARBON CENTERS-
dc.subjectENANTIOSELECTIVE CONSTRUCTION-
dc.subjectACIDS-
dc.subjectBIS(OXAZOLINES)-
dc.subjectALKYLATION-
dc.subjectKETOIMINES-
dc.subjectCOMPLEXES-
dc.titleAsymmetric formation of tert-alkylamines from serinols by a dual function catalyst-
dc.typeArticle-
dc.identifier.wosid000324894200046-
dc.identifier.scopusid2-s2.0-84884600094-
dc.type.rimsART-
dc.citation.volume49-
dc.citation.issue83-
dc.citation.beginningpage9669-
dc.citation.endingpage9671-
dc.citation.publicationnameCHEMICAL COMMUNICATIONS-
dc.identifier.doi10.1039/c3cc45099f-
dc.contributor.localauthorKang, SungHo-
dc.contributor.nonIdAuthorYou, Young Suk-
dc.contributor.nonIdAuthorKim, Tae Woo-
dc.type.journalArticleArticle-
dc.subject.keywordPlusQUATERNARY CARBON CENTERS-
dc.subject.keywordPlusENANTIOSELECTIVE CONSTRUCTION-
dc.subject.keywordPlusACIDS-
dc.subject.keywordPlusBIS(OXAZOLINES)-
dc.subject.keywordPlusALKYLATION-
dc.subject.keywordPlusKETOIMINES-
dc.subject.keywordPlusCOMPLEXES-
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CH-Journal Papers(저널논문)
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