Asymmetric formation of tert-alkylamines from serinols by a dual function catalyst

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Consecutive intramolecular desymmetrization and kinetic resolution of 2-substituted N-phenoxycarbonylserinols have been achieved in one-pot by a single chiral catalyst, bisox(7)-CuCl2, to form oxazolidinones with remarkable enantioselectivities (94-99% ee) as tert-alkylamine building blocks. The process culminates in a dual-function of the chiral catalyst.
Publisher
ROYAL SOC CHEMISTRY
Issue Date
2013
Language
English
Article Type
Article
Keywords

QUATERNARY CARBON CENTERS; ENANTIOSELECTIVE CONSTRUCTION; ACIDS; BIS(OXAZOLINES); ALKYLATION; KETOIMINES; COMPLEXES

Citation

CHEMICAL COMMUNICATIONS, v.49, no.83, pp.9669 - 9671

ISSN
1359-7345
DOI
10.1039/c3cc45099f
URI
http://hdl.handle.net/10203/255296
Appears in Collection
CH-Journal Papers(저널논문)
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