Ruthenium-catalyzed selective imine synthesis from nitriles and secondary alcohols under hydrogen acceptor- and base-free conditions

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We report a method for the selective synthesis of imines from nitriles and secondary alcohols using a hydrogen-transfer strategy. The imine bond is efficiently formed between the nitrogen atom of nitrile and the alpha-carbon of secondary alcohol, catalyzed by a ruthenium dihydride complex with pyridine as a stabilizing ligand.
Publisher
CHINESE CHEMICAL SOC
Issue Date
2016
Language
English
Article Type
Article
Citation

ORGANIC CHEMISTRY FRONTIERS, v.3, no.4, pp.475 - 479

ISSN
2052-4129
DOI
10.1039/c5qo00378d
URI
http://hdl.handle.net/10203/251864
Appears in Collection
CH-Journal Papers(저널논문)
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