Conversion Reaction of Nanoporous ZnO for Stable Electrochemical Cycling of Binderless Si Microparticle Composite Anode

Cited 2 time in webofscience Cited 0 time in scopus
  • Hit : 111
  • Download : 0
Binderless, additiveless Si electrode design is developed where a nanoporous ZnO matrix is coated on a Si microparticle electrode to accommodate extreme Si volume expansion and facilitate stable electrochemical cycling. The conversion reaction of nanoporous ZnO forms an ionically and electrically conductive matrix of metallic Zn embedded in Li2O that surrounds the Si microparticles. Upon lithiation, the porous Li2O/Zn matrix expands with Si, preventing extensive pulverization, while Zn serves as active material to form LixZn to further enhance capacity. Electrodes with a Si mass loading of 1.5 mg/cm2 were fabricated, and a high initial capacity of ∼3900 mAh/g was achieved with an excellent reversible capacity of ∼1500 mAh/g (areal capacity ∼1.7 mAh/cm2) beyond 200 cycles. A high first-cycle Coulombic efficiency was obtained owing to the conversion reaction of nanoporous ZnO, which is a notable feature in comparison to conventional Si anodes. Ex situ analyses confirmed that the nanoporous ZnO coating maintained the coalescence of SiMPs throughout extended cycling. Therefore, the Li2O/Zn matrix derived from conversion-reacted nanoporous ZnO acted as an effective buffer to lithiation-induced stresses from volume expansion and served as a binder-like matrix that contributed to the overall electrode capacity and stability. © 2018 American Chemical Society.
Publisher
AMER CHEMICAL SOC
Issue Date
2018-11
Language
English
Article Type
Article
Citation

ACS NANO, v.12, no.11, pp.10903 - 10913

ISSN
1936-0851
DOI
10.1021/acsnano.8b03951
URI
http://hdl.handle.net/10203/248716
Appears in Collection
EEW-Journal Papers(저널논문)
Files in This Item
There are no files associated with this item.
This item is cited by other documents in WoS
⊙ Detail Information in WoSⓡ Click to see webofscience_button
⊙ Cited 2 items in WoS Click to see citing articles in records_button

qr_code

  • mendeley

    citeulike


rss_1.0 rss_2.0 atom_1.0