Immobilization of uranium(VI) in a cementitious matrix with nanoscale zerovalent iron (NZVI)

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We developed a novel solidification and stabilization process using a nanoscale zerovalent iron (NZVI)cement system for reductive immobilization of hexavalent uranium (U(VI)) in a soil-cement matrix. The NZVI suspension without cement demonstrated high removal efficiency (100% in 2 h) and fast removal kinetics (53.7 Lm(-2) d(-1)), which surpassed those of other Fe-containing minerals (i.e., green rust, mackinawite, magnetite, and pyrite). Significant removal of aqueous U(VI) was observed in NZVI-cement slurries and minimal adsorbed U was desorbed by a bicarbonate/carbonate (CARB) solution. Surface analysis using scanning electron microscopy and X-ray photoelectron spectroscopy revealed U distributed homogeneously on the surface of the NZVI-cement and transformed considerably from U(VI) to reduced U species by coupled oxidation of Fe(0)/Fe(II) to Fe(III). Furthermore, the increase in pH and NZVI concentration, and presence of humic acid resulted in the enhanced U(VI) reduction in NZVI-cement slurries. The NZVI-cement system was tested with a soil matrix, resulting in successful immobilization of aqueous U(VI) in both batch and column experiments. Moreover, the U(VI) removed in the NZVI-cement system was not leached out by the CARB solution during long-term experiments. The results suggest an NZVI-cement system could represent a promising remediation alternative for effective and stable immobilization of U(VI) in contaminated sites. (C) 2018 Elsevier Ltd. All rights reserved.
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Issue Date
2019-01
Language
English
Article Type
Article
Citation

CHEMOSPHERE, v.215, pp.626 - 633

ISSN
0045-6535
DOI
10.1016/j.chemosphere.2018.10.073
URI
http://hdl.handle.net/10203/248232
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