Charge carrier dynamics in PffBT4T-2OD: PCBM organic solar cells

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We investigate the charge carrier dynamics of inverted organic solar cells (OSCs) based on PffBT4T-2OD: PCBM and PTB7: PCBM - the two leading systems among the OSCs based on polymer-fullerene bulk-heterojunction - to elucidate the origin of their performance difference. Transient absorption spectroscopy (TAS) and photo-electrochemical impedance spectroscopy (photo-EIS) were employed to unravel the photo-physics that govern the cell operation of these two highly efficient bulk heterojunction OSCs. While photo-EIS indicates that the two systems under study exhibit similar behavior in terms of recombination, TAS results reveal that PffBT4T-2OD: PCBM systems not only have higher charge generation rate but also more efficient charge transfer than PTB7: PCBM systems, leading to the power conversion efficiency of PffBT4T-2OD: PCBM-based OSCs (9.16%) that is higher than that of PTB7: PCBM-based OSCs (6.44%).
Publisher
Elsevier BV
Issue Date
2018-11
Article Type
Article
Citation

Organic Electronics, v.62, pp.441 - 447

ISSN
1566-1199
DOI
10.1016/j.orgel.2018.08.018
URI
http://hdl.handle.net/10203/247633
Appears in Collection
EE-Journal Papers(저널논문)
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