ISOMERIZATION OF 1-HEXENE CATALYZED OVER POLYMER-SUPPORTED RUCL2(PPH3)3

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dc.contributor.authorAhn, Jou-Hyeonko
dc.contributor.authorJo, Young-Doko
dc.contributor.authorIhm, Son-Kiko
dc.date.accessioned2011-06-27T06:15:33Z-
dc.date.available2011-06-27T06:15:33Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued1991-07-
dc.identifier.citationKOREAN JOURNAL OF CHEMICAL ENGINEERING, v.8, no.3, pp.183 - 187-
dc.identifier.issn0256-1115-
dc.identifier.urihttp://hdl.handle.net/10203/24194-
dc.description.abstractPolymer-supported ruthenium catalyst was prepared by anchoring dichlorotris(triphenylphosphine)ruthenium, RuCl2(PPh3)3, onto the phosphinated polystyrene bead. The polymer-supported RuCl2(PPh3)3 could be reused several times with only small loss of catalytic activity in the isomerization of 1-hexene. The activity rather increased during the few initial runs. In both homogeneous and heterogenized catalysts, an induction period was required to initiate the isomerization. The catalyst efficiency was promoted in the mixture of good swelling solvent and potent hydrogen donor. Upon heterogenizing, the activity was reduced by a factor of 2.0-8.2.-
dc.description.sponsorshipThis work has been carried out as a cooperative research between KAIST and Technical University of Braunschweig of West Germany. The authors wish to acknowledge a financial support from the Korea Ministry of Science and Technology.en
dc.languageEnglish-
dc.language.isoen_USen
dc.publisherKOREAN INSTITUTE CHEMICAL ENGINEERS-
dc.titleISOMERIZATION OF 1-HEXENE CATALYZED OVER POLYMER-SUPPORTED RUCL2(PPH3)3-
dc.typeArticle-
dc.identifier.wosidA1991GE84100009-
dc.identifier.scopusid2-s2.0-51249176819-
dc.type.rimsART-
dc.citation.volume8-
dc.citation.issue3-
dc.citation.beginningpage183-
dc.citation.endingpage187-
dc.citation.publicationnameKOREAN JOURNAL OF CHEMICAL ENGINEERING-
dc.identifier.doi10.1007/BF02706681-
dc.embargo.liftdate9999-12-31-
dc.embargo.terms9999-12-31-
dc.contributor.localauthorIhm, Son-Ki-
dc.contributor.nonIdAuthorAhn, Jou-Hyeon-
dc.contributor.nonIdAuthorJo, Young-Do-
dc.type.journalArticleArticle-
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CBE-Journal Papers(저널논문)
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